NATURAL DYEING OF TEXTILES

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Introduction

Some of the well known ancient dyes include madder, a red dye made from the roots of the Rubia tinctorum, blue indigo from the leaves of Indigofera tinctoria, yellow from the stigmas of the saffron plant, and dogwood, an extract of pulp of the dogwood tree. The first use of the blue dye, woad, beloved by the Ancient Britons, may have originated in Palestine where it was found growing wild. The most famous and highly prized colour through the age was Tyrian purple, noted in the Bible, a dye obtained from the spiny dye-murex shellfish. The Phoenicians prepared it until the seventh century, when Arab conquerors destroyed their dyeing installations in the Levant. A bright red called cochineal was obtained from an insect native to Mexico. All these produced high-quality dark colours. Until the mid-19th century all dyestuffs were made from natural materials, mainly vegetable and animal matter.

Today, dyeing is a complex, specialised science. Nearly all dyestuffs are now produced from synthetic compounds. This means that costs have been greatly reduced and certain application and wear characteristics have been greatly enhanced. But many practitioners of the craft of natural dying (i.e. using naturally occurring sources of dye) maintain that natural dyes have a far superior aesthetic quality which is much more pleasing to the eye. On the other hand, many commercial practitioners feel that natural dyes are non-viable on grounds of both quality and economics. In the West, natural dyeing is now practised only as a handcraft, synthetic dyes being used in all commercial applications. Some craft spinners, weavers, and knitters use natural dyes as a particular feature of their work.

In many of the world’s developing countries, however, natural dyes can offer not only a rich and varied source of dyestuff, but also the possibility of an income through sustainable harvest and sale of these dye plants. Many dyes are available from tree waste or can be easily grown in market gardens. In areas where synthetic dyes, mordants (fixatives) and other additives are imported and therefore relatively expensive, natural dyes can offer an attractive alternative.

Dyeing of textiles Practical Action

The knowledge required for sourcing and extracting such dyes and mordants is, however, often not available as extensive research work is required to identify suitable plants, minerals, etc. In Zambia for example, there is a wealth of plants available for producing

natural dyes, but due to lack of knowledge of the processes involved in harvesting and processing the plants, little use is made of this natural resource. In some countries, such as India, Nigeria and Liberia, where this research has been carried out, or where there exists a tradition of natural dyeing, natural dyes and mordants are used widely.

Types of textiles suitable for dying

Natural dyes can be used on most types of material or fibre but the level of success in terms of fastness and clarity of colour varies considerably. Users of natural dyes, however, tend to also use natural fibres, and so we will look in more detail at this group. Natural fibres come mainly from two distinct origins, animal origin or vegetable origin. Fibres from an animal origin include wool, silk, mohair and alpaca, as well as some others which are less well known. All animal fibres are based on proteins. Natural dyes have a strong affinity to fibres of animal origin, especially wool, silk and mohair and the results with these fibres are usually good. Fibres of plant origin include cotton, flax or linen, ramie, jute, hemp and many others. Plant fibres have cellulose as their basic ingredient. Natural dyeing of certain plant based textiles can be less successful than their animal equivalent. Different mordanting techniques are called for with each category. When a blend of fibre of both animal and plant origin is being dyed, then a recipe should be chosen which will accentuate the fibre which is required to be dominant.

Equipment needed for home dyeing and very small-scale commercial dyeing

Most equipment needed for dyeing fabrics at home, or at the very small-scale commercial level, can be found in almost any market place throughout the world. The following is a list of the equipment requirements and a brief explanation of their use.

1. • Heat source. This can be any type of cooking stove; gas, wood, kerosene, charcoal, electricity. This is used for heating the liquid used during mordanting and dyeing.
2. • Pestle and mortar. Used for milling the natural dye or minerals, where this is called for.
3. • Mordanting and dyeing pans. Stainless steel or enamel pans are the most suitable for dyeing. The size of pan depends upon the quantities of fabric that will be dyed. Do not use pans made from copper, aluminium or iron, unless absolutely necessary, as these metals have properties which can change the colour of the dye.
4. • tirring rods. Stainless steel or glass rods are best as they can be cleaned and used for different colour dyes. If wooden stirring rods are used then there should be a different spoon for each colour.
5. • Thermometer. This is used to measure the temperature of the liquid during mordanting and dyeing. A long thermometer (to reach the liquid at the bottom of the pan) is preferred, with a range of 0 – 100oC (32 – 210oF).
6. • Measuring jugs. These are used to measure the quantities of liquid called for in the recipe. Sometimes precise quantities are called for.
7. • Storage containers. Used for storing the dyestuffs and mordants. Large glass and plastic jars are ideal. Some mordants and dyes are sensitive to light and should therefore be stored in sealed light-proof containers.
8. • Plastic bowls and buckets. A variety of plastic bowls or buckets of varying sizes are useful when wetting or rinsing fabrics.
9. • Strainer. Used for straining the liquid off the dyestuff in the dyebath.
10. • Weighing scales. Used for obtaining the correct quantities as specified in the recipe. A scales with metric and imperial measurement is useful as conversions from one system to the other are not then needed.
11. • Protective equipment. Gloves for holding hot pans will prevent burns. An apron will protect your clothing. Rubber gloves will prevent skin irritation caused by mordants, and

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1. will also prevent you from dyeing your hands. A face mask can cut down the amount of fumes or powder inhaled during the dyeing process.

Mordants

Few natural dyes are colour-fast with fibres. Mordants are substances which are used to fix a dye to the fibres. They also improve the take-up quality of the fabric and help improve colour and light-fastness. The term is derived from the Latin mordere, to bite. Some natural dyes, indigo for example, will fix without the aid of a mordant; these dyes are known as ‘substantive dyes’. Others dyes, such as madder and weld, have a limited fastness and the colour will fade with washing and exposure to light.

Traditionally, mordants were found in nature. Wood ash or stale urine may have been used as an alkali mordant, and acids could be found in acidic fruits or rhubarb leaves (which contain oxalic acid), for example. Nowadays most natural dyers use chemical mordants such as alum, copper sulphate, iron or chrome (there are concerns, however about the toxic nature of chrome and some practitioners recommend that it is not used).

Mordants are prepared in solution, often with the addition of an ‘assistant’ which improves the fixing of the mordant to the yarn or fibre. The most commonly used mordant is alum, which is usually used with cream of tartar as an additive or assistant. Other mordants are:

1. • Iron (ferrous sulphate)
2. • Tin (stannous chloride)
3. • Chrome (bichromate of potash)
4. • Copper sulphate
5. • Tannic acid
6. • Oxalic acid

Using a different mordant with the same dyestuff can produce different shades, for example;

1. • Iron is used as a ‘saddener’ and is used to darken colours.
2. • Copper sulphate also darkens but can give shades which are otherwise very difficult to obtain.
3. • Tin brightens colours.
4. • Tannic acid, used traditionally with other mordants, will add brilliancy.
5. • Chrome is good for obtaining yellows.
6. • Oxalic acid is good for extracting blues from berries.
7. • Cream of Tartar is not really a mordant but is used to give a lustre to wool.

Mordants are often poisonous, and in the dye-house they should be kept on a high shelf out of the reach of children. Always use protective clothing when working with mordants and avoid breathing the fumes.

The mordant can be added before, during or after the dyeing stage, although most recipes call for mordanting to take place prior to dyeing. It is best to follow the instructions given in the recipe being used or experiment on a sample before carrying out the final dyeing. Later in this brief we will explain how the mordant is mixed and used as part of the dyeing process.

These chemical mordants are usually obtained from specialist suppliers or from chemists. Where this is prohibitive, due to location or cost, natural mordants can be used. There are

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a number of plants and minerals which will yield a suitable mordant, but their availability will be dependent upon your surroundings. Some common substitutes for a selection of mordants are listed below.

1. • Some plants, such as mosses and tea, contain a small amount of aluminium. This can be used as a substitute to alum. It is difficult to know, however, how much aluminium will be present and experimentation may be necessary.
2. • Iron water can be used as a substitute to ferrous sulphate. This can be made simply by adding some rusty nails and a cupful of vinegar to a bucket-full of water and allowing the mixture to sit for a couple of weeks.
3. • Oak galls or sumach leaves can be used a substitute to tannic acid.
4. • Rhubarb leaves contain oxalic acid.